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The title compounds were prepared and their crystal structures determined from low temperature single crystal X-ray data. The structures contain the anions SbCl 6  -  and AlCL 4  - and the novel interhalogen cations I 3 Cl 2  +  and I 3 Br 2  +  . Anions and cations are linked to infinite chains by weak covalent bonds.

zeitschrift für naturforschung b

Interhalogen-Kationen: Darstellung und Kristallstrukturen (143 K) von I 3 Cl 2 SbCl 6 , I 3 Cl 2 AlCl 4  und I 3 Br 2 SbCl 6  / Interhalogen Cations: Preparation and Crystal Structures (143 K) of I 3 Cl 2 SbCl 6 , I 3 Cl 2 AlCl 4  and I 3 Br 2 SbCl 6