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In Mn(CO) 5 Br one or two CO groups could be replaced by Me 2 AsCl. From Me 2 AsCl-Mn(CO) 4 Br with carbonyl metalates, or from Mn(CO) 5 Br with organometal dimethylarsenides, the arsenic bridged dinuclear complexes L n M-AsMe 2 -Mn(CO) 4 Br with L n M = CrCp(CO) 3 , MoCp(CO) 3 , WCp(CO) 3 , and Mn(CO) 5  were obtained. Upon attempts to convert these to metal-metal bonded compounds the Cr-As-Mn complex decomposed whereas the Mn-As-Mn complex was spontaneously converted to (CO) 4 Mn[μ-AsMe 2 , μ-Br]Mn(CO) 4 .

Arsenverbrückte zweikernige Mn(CO) 4 Br-Komplexe / Arsenic Bridged Dinuclear Mn(CO) 4 Br Complexes