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A new modification of CuI · py was prepared by the reaction of a saturated solution of CuI in CH 3 CN with a solution of pyridine in ethanol at 60 °C. It crystallizes monoclinic with four formula units in the space group P2 1 /c. (CuI · py)∞ forms a polymeric ribbon structure. Contrary to the cubane-like tetrameric modification, (CuI · py)∞ does not show luminescence thermochromism. The luminescence properties of both modifications of Cul · py are interpreted.

zeitschrift für naturforschung b

Strukturisomere von Kupfer(I)iodid · Pyridin und ihre Lumineszenzeigenschaften. Darstellung und Kristallstruktur einer neuen Modifikation von Cul · NC 5 H 5  /  Structural Isomers of Copper(I) Iodide Pyridine and their Luminescence Properties Synthesis and Crystal Structure of a New Modification of Cul · NC 5 H 5