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The interaction of the transition metal dimethylarsine sulfides Cp(CO) 2 PMe 3 M-As(S)Me 2  (M = Mo, W) with acetylhalides yields cationic complexes bearing the Me 2 AsSC(O)Me or Me 2 AsCl(Br) ligand, respectively. In a first step, the salt [Cp(CO) 2 PMe 3 M-AsMe 2 SC(O)Me] ⊕ X ⊖  1a-c (X = Cl, Br) is formed, which is converted by a second mole MeC(O)X into salts [Cp(CO) 2 PMe 3 M-AsMe 2 X] ⊕ X ⊖  2a-c, with (Me 2 CO) 2 S elimination. The brominated complex 2b can also be obtained by the addition of Br 2  to Cp(CO) 2 PMe 3 W-AsMe 2 . The composition and structure of the ionic dihalogen adducts are established by NMR and IR data and by conductivity measurements.

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Übergangsmetall-substituierte Phosphane, Arsane und Slibane, XXIV [1] Funktionelle Arsanliganden durch Reaktion von Übergangsmetalldimethylarsinsulfiden mit Aeetylhalogenid [2] / Transition Metal Substituted Phosphanes, Arsanes and Stibanes, XXIV [1] Functional Arsane Ligands via Reaction of Transition Metal-Dimethylarsinesulfides with Acetylhalide [2]