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The 1:1 adduct formed by triphenylphosphine with bis(η 3 -allyl)palladium disproportionates at 0 °C in toluene to give the title compound. A crystal structure determination confirms the presence of a Pd-Pd bond and bridging η 3 -allyl groups

The Structure of [η 3 -C 3 H 5 PdP(C 6 H 5 ) 3 ] 2