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The cationic dicarbonyl complexes [Rh(CO) 2 (R 2 PCH 2 ) 3 CRʹ]PF 6  (R = C 6 H 5 ; Rʹ = CH 3 , -CH 2 PR 2 ), formed by high pressure synthesis from RhCl 3 (H 2 O) 3 , CO and (R 2 PCH 2 ) 3 CRʹ react with liquid ammonia at 20 °C to give the carbamoyl complexes Rh(CO)(CONH 2 )(R 2 PCH 2 ) 3 CRʹ. At 100 °C in liquid ammonia the carbamoyl-carbonyl complexes Rh(CO)(CONH 2 )(R 2 PCH 2 ) 3 CRʹ form the CO-bridged, dinuclear compounds (μ-CO) 2 [Rh(R 2 PCH 2 ) 3 CRʹ] 2 . Upon treatment of Rh(CO)(CONH 2 )(R 2 PCH 2 ) 3 CRʹ with CH 3 OH the carbomethoxo carbonyl complexes Rh(CO)(COOCH 3 )(R 2 PCH 2 ) 3 CRʹ are obtained. The new compounds were characterised, as far as possible, by their IR, Raman and  31 P NMR spectra.

zeitschrift für naturforschung b

Dicarbonyl-, Carbamoyl-carbonyl-und Carbomethoxo-carbonyl-Komplexe des Rhodiums mit tri-und tetratertiären Phosphinliganden [1] Dicarbonyl-, Carbamoyl-carbonyl-and Carbomethoxo-carbonyl Complexes of Rhodium with Tri-and Tetratertiary Phosphine Ligands [1]