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a,β Unsaturated ketones are selectively hydrogenated to ketones in homogeneous bulk-catalysis under mild conditions by iridium-and ruthenium complexes. The range of mean turnover is from 6 to 196 depending on substrate, catalyst and reaction conditions. Selectivity ketone/alcohol depends on the degree of conversion and exceeds 100 on conversion of 90%.

zeitschrift für naturforschung b

Selektive Bulk-Hydrierung von a,β-ungesättigten Ketonen zu Ketonen mit homogenen Ir- und Ru-Katalysatoren / Selective Bulk-Hydrogenation of a,β Unsaturated Ketones to Ketones with Homogeneous Ir and Ru Catalysts