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A theoretical model for the electrochemical synthesis of transition metal complexes in low oxidation states has been developed on the basis of Pearson’s HSAB concept. A MO description is used to discuss the important practical implications of the model.

zeitschrift für naturforschung b

Elektrochemische Synthesen, II [1]. Theoretische Aspekte der elektrochemischen Synthese von Komplexen / Electrochemical Syntheses, II [1]. Theoretical Aspects of the Electrochemical Synthesis of Complexes