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Antimony(V) Chloride, Acetoacetanilide At room temperature acetoacetanilide and antimony(V) chloride form a 1:1-(1) and a 1:2-adduct (2). These adducts react to the heterocycles C 10 H 10 Cl 4 NO 2 Sb (3) and C 10 H 9 Cl 5 NO 2 Sb (4). 3 exists in solution in two stereoisomers. The Free Energy of Activation for the transformation of the isomers is estimated.

Reaktionen von SbCl 5 mit Acetoaeetanilid / Reactions of SbCl 5 with Acetoacetanilide