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The migratory aptitude of halogens and simple nucleophilic substituents X in the molecular ions of alkynes 1-11 and alkenes 12-17 was investigated by electron-impact mass spectrometry using low and high resolution, metastable analysis and  2 H-labelling.

zeitschrift für naturforschung b

Massenspektrometrische Untersuchungen an ungesättigten Kohlenwasserstoffen: Halogen-Wanderung bei Acetylenen und Olefinen / Mass Spectrometric Investigations on Unsaturated Hydrocarbons: Halogen Migration in the Molecular Ions of Acetylenes and Alkenes