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Quinolinium Salts, Redox Reactions Quaternary salts of 3-quinolinecarboxamide and 3-quinolinecarbonitrile react after addition of ZnCl 2  with ethanol (or 2-propanol) to the corresponding 1,4-dihydroquinoline and ethanol (or propanone). This hydride transfer can be achieved with aluminium-triisopropoxide, too. Lipophilic insertionproducts (4,5,7,8) react with ethanol (or 2-propanal) after ZnCl 2  addition to quinolinium-alcoxides, and then to the 1,4-dihydro-quinoline and ethanal (or propanone).

Redoxreaktion zwischen Chinolinium-Salzen und Alkoholaten / Redoxreaction between Quinolinium Salts and Alcoholates