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From the iridium complexes [(1,5-C 8 H 12 )IrCl] 2 , [(C 8 H 14 ) 2 IrCl] 2  and [(C 6 H 5 ) 3 P] 2 lr(CO)Cl, and the ylides (CH 3 ) 3 P = CH 2  and (CH 3 ) 3 P = N-P(CH 3 ) 2  = CH 2 , a number of organoiridium compounds has been synthesized. Whereas with (CH 3 ) 3 P = CH 2  the transylidation reaction is very slow and simple addition with formation of sparingly soluble products prevails, the double ylide forms cyclic complexes quite readily. These ylide chelates were characterized by analytical and spectroscopic data.

Einige neue Iridium-Komplexe von Phosphor-yliden /Some New Iridium Complexes of Phosphorus Ylides