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The 2-methylthio-ethoxycarbonyl (Mtc) amino protecting function of dipeptide esters (3) is converted into 2-thiocyanato-ethoxycarbonyl derivatives (6) b y treatment with cyanogen bromide. This behaviour of the Mtc-group contrasts with the cleavage of the N-acyl methionyl peptides, due to the differing nucleophilicity of the respective carbonyl oxygens

zeitschrift für naturforschung b

Modifikation der N-terminalen 2-Methylthio-ethoxycarbonyl-(Mtc)-Sehutzgruppe von Peptiden mit Bromcyan / Modification of the N-Terminal 2-Methylthioethoxycarbonyl Protective Function of Peptides Using Cyanogen Bromide