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The reaction of trimethylsilylsulfonamides with halodiorganylboranes leads to the corresponding sulfonamidoboranes and halotrimethylsilane. Trimethylsilylsulfonamides are prepared by reaction of the corresponding sulfonyl chlorides with primary amines, followed by the addition of chlorotrimethylsilane in the presence of excess triethylamine.  1 H,  11 B NMR spectra and mass spectra are reported

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Umsetzungen von Metall- und Metalloidverbindungen mit mehrfunktionellen Molekülen, XXIV [1] Synthese von Sulfonamidoboranen und Sulfonamidosilanen / Reactions of Metal and Metalloid Compounds with Polyfunctional Molecules, XXIV [1] Synthesis of Sulfonamidoboranes and Sulfonamidosilanes