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The title compound N,N-bis(trimethylstannyl)trifluoromethanesulfonamide (1) reacts with S 2 Cl 2 , SOCl 2  and SO 2 Cl 2  in a molar ratio 2:1 to yield the compoundsS 2 Cl 2  a twelve-membered ring 6. These are the largest neutral sulfur-nitrogen rings of coordination number two at the sulfur atoms known to date. 3 reacts with SOCI2 under migration of a methyl group from the tin to a sulfur atom to yield CF 3 SO 2 (R 3 Sn)NS(CH 3 )NSO 2 CF 3  (7).

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Reaktioneil mit N,N-Bis(trimethylstannyl)trifluormethansulfonamid und die Röntgenstrukturanalyse eines zwölfgliedrigen Schwefel-Stickstoff-Ringes / Reactions with N,N-Bis(trimethylstannyl)trifluoromethanesulfonamide and the X-ray Structure of a Twelve-Membered Sulfur-Nitrogen-Ring