English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Tools annual

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Presents the access of premium content as premium feature

Premium Content

Global: Zendy Plus annual

Global: Zendy Free Plan

[Mn(CO) 3 (R 2 PCH 2 ) 3 CCH 3 ]ClO 4  (1a) (R = C 6 H 5 ) reacts with NaBH 4  on UV irradiation to yield HMn(CO) 2 (R 2 PCH 2 ) 3 CCH 3  (2a). [Mn(CO) 3 (R 2 PCH 2 ) 3 CCH 3 ]BR 4  (1b) gives only decomposition products. Boiling of 1a or b and NaOH in acetone/water does nots give 2a but the new hydride HMn(CO) 3 (R 2 PCH 2 ) 2 C(CH 3 )CH 2 PR 2  (3a). This compound cannot be prepared on ultraviolet irradiation of a solution of 1a or b and NaBH 4  in methyl alcohol or acetone. The analogous deutendes DMn(CO) 2 (R 2 )PCH 2 ) 3 CCH 3  (2b) and DMn(CO) 3 (R 2 PCH 2 ) 2 C(CH 3 )CH 2 PR 2  (3b) were also prepared. The new compounds were characterized by their IR, Raman,  1 H NMR and  31 P NMR spectra.

zeitschrift für naturforschung b

Komplexchemie polyfunktioneller Liganden, 52 [1]. Hydrido- und Deuterido-mangan(I)-carbonyl-Komplexe des 1.1.1- Tris (diphenylphosphinomeihy 1) ethans / Complex Chemistry of Polyfiinctional Ligands, 52 [1]. Hydrido- and Deuterido-manganese(I)-carbonyl Complexes of 1,1,1 -Tris(diphenylphosphinomethyl)ethane