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Low temperature photolysis of (η 5 -C 5 H 5 )Co(CO) 2  with diphenyldiazomethane in tetrahydrofurane yields μ-carbonyl-μ-diphenylmethylene-bis(η 5 cyclopentadienylcobalt) (Co-Co) and μ 3 -earbonyl-μ 3 -(diphenylmethylenehydrazido)(N.N.N)-cyclotris(η 5 -cyclo-pentadienylcobalt) (3 Co-Co). The bridged μ-diphenylmethylene complex is also formed by thermal reaction of (η 5 -C 5 H 5 )Co(CO) 2  with diphenyldiazomethane in boiling benzene.

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Komplexchemie reaktiver organischer Verbindungen, XXV [1] Stabilisierung von Diphenylmethylen und Diphenyldiazomethan in Carbonylcobalt-Komplexen / Complex Chemistry of Reactive Organic Compounds, XXV [1] Stabilization of Diphenylmethylene and Diphenyldiazomethane in Carbonyl Cobalt Complexes