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The Mössbauer parameters of (CO) 4 FeL complexes were determined, were L are carbon ligands. The isomer shifts show strong π-interactions, if backbonding from the substituenta of the carbon atom is possible. The quadrupole splitting of [(CO) 4 FeCONMe 2 ] 2 Ni indicates a coordination number of six for the iron atoms with iron-nickel interactions.

zeitschrift für naturforschung b

Mössbauer-Untersuchungen an Eisencarbonylkomplexen mit Carben-, Alkoxycarbonyl- und Carbamoylliganden / Mössbauer Investigations of Iron Carbonyl Complexes with Carbene, Alkoxycarbonyl and Carbamoyl Ligands