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The title compounds have been prepared and structurally characterized. Na 2 CuP crystallizes in the Na 2 CuAs-structure type/(Cmcm) forming infinite Cu—P-zigzag-chains. In the silver compounds we found analogous Ag—E(V)-chains in a cell with atomic positions, which slightly violate the above symmetry.

zeitschrift für naturforschung b

Darstellung und Kristallstruktur von Na 2 CuP, K 2 AgAs, K 2 AgSb und K 2 AgBi / Preparation and Crystal Structure of Na 2 CuP, K 2 AgAs, K 2 AgSb, and K 2 AgBi