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Starting with (1- 14 C)ethanol (2z) octachloro-(2- 14 C)propane (1 z) is synthesized according to Scheme 1. The skeleton of 1 z is rearranged by AlCl 3 . The equilibrium octachloropropane (1)/tetrachloromethane (11) + perchloroethylene (12) is proved by gaschromatography.

zeitschrift für naturforschung b

Markierte Verbindungen, XXVII Darstellung und katalytische Spaltung des Octachlor-(2- 14 C)propan / On Labelled Compounds, XXVII Synthesis and Catalytic Cleavage of Octachloro-(2- 14 C)propane