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The photochemical conversion of 2-sulfinyl substituted benzaldehydes into benzoic acids in a new type of redox reaction is discribed in which a transfer of an oxygen atom, originally attached to sulphur, takes place by insertion into the C-Η bond of the aldehyde function located in ortho position. Influences of substituents at the sulfinyl group in this photoreaction which seems to be limitated to aldehydes are discussed briefly.

zeitschrift für naturforschung b

Photoreaktionen 2-sulfinylsubstituierter Benzaldehydeeine neue photoinduzierte Sauerstoff-Transfer-Reaktion / Photoreactions of 2-Sulfinyl Substituted Benzaldehydes aNew Photoinduced Oxygen-Transfer Reaction