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Both mononuclear Cr(CO) 5 (C 2 H 2 N 4 ) and binuclear [Cr(CO) 5 ] 2 (C 2 H 2 N 4 ) are formed when s-tetrazine (C 2 H 2 N 4 ) is added to a photolysed solution of Cr(CO) 6  in diethyl ether. A centrosymmetric structure is proposed for the binuclear, s-tetrazine-bridged complex [Cr(CO) 5 ] 2 (C 2 H 2 N 4 ). The corresponding molybdenum and tungsten compounds are also described

zeitschrift für naturforschung b

Übergangsmetallkomplexe mit N-haltigen Liganden, XI. Pentacarbonylchrom-Komplexe des s-Tetrazins und verwandte Verbindungen. / Transition Metal Complexes of N-Containing Ligands, XI. Pentacarbonylchromium Complexes of s-Tetrazine and Related Compounds