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Photokinetic experiments show that the deamination reaction of a series of 4-Amino-3-methylthio-1.2.4-triazin-5(4 H)-ons (1 a—e) is dependent on oxygen and nature of solvent. Experiments with a series of 6-tert-Butyl-3-methylthio-1.2.4-triazin-5(4 H)-ons (3 a—e) indicate that the formation of 6-tert-Butyl-3-methylthio-1.2.4-triazin-5-ons (2 d) occurs only in the case of an N—N-bond, but is, however, completely independent of the substituent on the nitrogen atom which is split off.

zeitschrift für naturforschung b

Beiträge zur ökologischen Chemie, CXIII 1 &lt;br /&gt;Photoinduzierte Desaminierungsreaktion an 4-Amino-3-methylthio-1.2.4-triazin-5(4H)-onen.: Photoinduced Deamination Reaction of 4-Amino-3-methylthio-1,2,4-triazin-5(4H)-ons