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The crystal structures of the title compounds were determined. Both compounds are isostructural and do not exist as dimers as previously assumed but as trimers in the form of six-membered rings in the chair conformation.

zeitschrift für naturforschung b

Die Kristall- und Molekülstrukturen von Dichlor(methylthio)boran und Dibrom(methylthio)boran.: The Crystal and Molecular Structures of Dichloro(methylthio)borane and Dibromo(methylthio)borane