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The reduction of the complexes C 5 H 5 Mn(CO) 2 L (L=P(C 6 H 5 ) 2 Cl, P(C 6 H 5 )(Et)Cl and P(C 6 H 5 )Cl 2 ) with Na in liquid NH 3  yields the complexes C 5 H 5 Mn(CO) 2 L′ (L′=P(C 6 H 5 ) 2 Na, P(C 6 H 5 )(Et)Na and P(C 6 H 5 )Na 2 ).

zeitschrift für naturforschung b

Austauschreaktionen an komplexgebundenen Liganden von Elementen der V. Hauptgruppe, V 1  Darstellung und Reaktionen von Komplexen des Typs π-C 5 H 5 Mn(CO) 2 L (L = Phosphid, Amid) / Exchange Reactions at Complexed Ligands of Elements of Group V B 1  / Preparation and Reactions of Complexes of the Type π-C 5 H 5 Mn(CO) 2 L (L = phosphide, amide)