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The N-alkyliminoalanes [tert-C 4 H 9 NAIH] 4 , [tert-C 4 H 9 NAID] 4 , [iso-C 3 H 7 NAIH] 6 , [C 2 H 5 NAlH] 8  and [CH 3 NAIH] n  have been prepared and intermediates such as Al 3 H 3 (N tert-C 4 H 9 )2(N tert-NHC 4 H 9 )2 and Al 8 H 10 (NC 2 H 5 ) 6 (NHC 2 H 5 ) 2  isolated. Cage structures and opened cages respectively are suggested on the basis of physical data.

Darstellung, Struktur und Eigenschaften von N-Alkyliminoalanen / Preparation, Structure and Properties of N-Alkyliminoalanes