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Preparation and properties of several metal vinylaryldithiophosphinates (CH 2 =CH)RPS 2 M/n (R: p-methoxyphenyl; p-ethoxyphenyl) are reported. Copolymerisation of the ammonium salt (CH 2 =CH)RP(S)SNH 4  (R = p- ethoxyphenyl) with methacrylic methylester gave polymers (M∼10,000) which acted as polyfunctional ligands thus giving soluble polymeric metal complexes (M ∼17,000) with Ni(II) and Co(II).

zeitschrift für naturforschung b

Metallkomplexe der Phosphinsäuren, XI. Metallvinylaryldithiophosphinate und polymere Komplexe polyfunktioneller Dithiophosphinsäuren  2 .: Metal Complexes of Phosphinic Acids, XI. Metal Vinylaryldithiophosphinates and Polymer Complexes of Polyfunctional Dithiophosphinic Acids