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A kinetic study was made of the primary step of the alkylation of benzene with propylene and ferric chloride as catalyst under homogeneous reaction conditions at several pressures up to 2 kbar. Initial reaction rate of cumene formation shows a minimum in the medium pressure range, thus indicating that product formation occurs via two different reaction paths with opposite pressure dependence.

Notizen: High Pressure Reactions, I Evidence for Two Concurrent Mechanisms in Lewis-Acid Catalyzed Alkylation of Aromatics with Olefins