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Mass-spectrometric investigations of the titel compounds show for the first time that SO-elimination is also possible from acyclic sulfonyl derivatives. From results of the defocusing technique follows that both this process and the elimination of CO 2  from the molecular ions are relative slow. Prove of these reactions can be found in the analysis of the metastable ions. These results are supported by substituent effects.

zeitschrift für naturforschung b

Spektroskopische Untersuchungen, X. Elektronenstoßinduzierte SO- und CO 2 -Eliminierungen aus N.N-Dimethyl-C-Arylsulfonylformamiden / Spectroscopic Investigations, X. Electron-impact Induced SO- and CO 2 -Elimination from N.N-Dimethyl-C-arylsulfonylformamides