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The He I photoelectron spectra of certain MeEHal 2  and Me 2 EHal compounds (E = (N), P, As, Sb; Hal = (F), Cl, Br, J; Me = CH 3 ) are interpreted in terms of a “composite molecule” approach derived for C 3v C s  systems. Although an “internal standard” is missing here, substituent group-orbitals (n Hal , C—H) may be classified with respect to their orientations in space (R, V, T). Ionisation energies are assigned according to this assumption.

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Photoelektronenspektren von Verbindungen der V. Hauptgruppe, ΙII Methylhalogenverbindungen MeEHaI 2  und Me 2 EHal / Photoelectron Spectra of Group V Compounds, III Methylhalogen Compounds MeEHal 2  and Me 2 EHal