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While the stable modification of CsNiF 3  is of green colour, a yellow phase is obtained by fluorination of CsNiCl 3  and decomposition of the product “CsNiF 4 ”, which contains Ni 4+  and Ni 3+  besides Ni 2+ . The two modifications have the 2L- and 9L-perovskite-structure, respectively, and are characterized by their X-ray patterns and low-temperature ligand field spectra. The differences in colours and spectral band positions are discussed with respect to the Ni-F-Ni bond angles

Präparative und spektroskopische Untersuchungen zur Dimorphie von CsNiF 3 .: Preparative and Spectroscopic Investigations on the Dimorphy of CsNiF 3