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Different mechanisms are considered to explain the formation of 5-deoxy-D-erythropentos-4-ulose in the γ-radiolysis of ribose-5-phosphate in aqueous solution. On the basis of deuterium labelling experiments one mechanism involving an enol as an intermediate could be excluded.

zeitschrift für naturforschung b

Notizen: Radiation Chemistry of DNA-Model Compounds, VII. On the Formation of 5-Deoxy-D-erythro-pentos-4-ulose and the Identification of Twelve Further Products from γ-Irradiated Aqueous Solutions of Ribose-5-phosphate