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The results of a bond order/bond distance relationship have been applied upon the known structure of Mo-O and Mo-S double bridge compounds. Mo-O t  bonds neighboring to Mo-S bridges are always about 0.03 Å longer than expected, indicating a π-bonding contribution in these bridges in contrary to the Mo-O double bridges.

Notizen: Contributions to the Chemistry of Mo and W, XVII.: Results on Mo-O and Mo-S Double Bridges