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A hydrogenation catalyst, operating under mild conditions can be prepared by dissolving H 2 PtCl 6  and SnCl 2  · 2 H 2 O in acetic acid. After injection of an unsaturated compound under a H 2 -atmosphere the active moiety of the catalyst is generated. No active moiety of catalyst is formed if the compound has a triple bond. But acetylenic derivatives are hydrogenated if the active moiety of the catalyst is first produced by hydrogenation of cyclohexene.

zeitschrift für naturforschung b

Notizen: Katalytische Hydrierung ungesättigter Verbindungen mit H 2 PtCl 6 -SnCl 2  · 2 H 2 O in Essigsäure / Catalytic Hydrogenation of Unsaturated Compounds with H 2 PtCl 6 -SnCl 2  · 2 H 2 O in Acetic Acid