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Reaction of 2-acetoxy-cyclohexa-3,5-dienones (“quinol-acetates”) with BF 3  or (CH 3 CO) 2 O/BF 3  in the presence of benzene derivatives (mesitylene, mesitol, 1,3-dimethoxybenzene, 1,3,5-trimethoxybenzene) yields biphenyl and diphenyl methane derivatives. The reasons for their formation are discussed.

zeitschrift für naturforschung b

Untersuchungen an Chinolacetaten, IV./ Quinol Acetates, IV: Dienon-Phenol-Umlagerung von o-Chinolacetaten in Gegenwart von Benzolderivaten&lt;br /&gt;Dienone-phenol Rearrangement of o-Quinol Acetates in the Presence of Benzene Derivatives&lt;br /&gt;(2.: Discussion of the Results)