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Pure alkaline earth halides MX 2  with M = Mg, Ca, Sr, Ba and X= Cl, Br, J were prepared by reaction of the metals with the corresponding ammonium halides in NH 3  as solvent. Brown Ca 2 PCl and dark-brown-violet Sr 2 PCl were obtained by reaction of metal chloride, metal and red phosphorous in the ratio 1:3:2. Analytical results, densities and lattice constants are given.

Darstellung und Eigenschaften von Ca 2 PCl und Sr 2 PCl / Preparation and Properties of Ca 2 PCl and Sr 2 PCl