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The reaction of 1,3,5-Trisilacyclohexanes containing Si—F and C—Cl groups and CH 3 MgCl starts with methylation of the Si—F group (in contrast to the reactions of the corresponding Si—Cl containing derivatives). At a certain degree of methylation a ring contraction starts at the C—Cl group.

NOTIZEN: Bildung und Reaktion Si-fluorierter 1.3.5-Trisila-cyclohexane / Formation and Reactions of Si-fluorinated 1,3,5-Trisilacyclohexanes