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Of the three diiodobenzenes the 1,3- and 1,4-isomer react with BI 3  to give the corresponding bis(diiodoboryl)benzenes. Due to the electronic acceptor properties of the BI 2 -group the formation of the 1,3-isomer is favored over the 1,4-product. Attempts to prepare the 1,2-bis(diiodoboryl)benzene resulted in the formation of a dibenzo-1,4-diborine derivative.

zeitschrift für naturforschung b

Redox-Untersuchungen an Jodboranen, XV / Redox-Studies on Iodoboranes, XV: Darstellung von Diborylaren-Verbindungen / Synthesis of Diborylarene Compounds