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Tris(trimethylsilyl)phosphane reacts with trimethylgermaniumchloride and trimethyltinchloride with redistribution of the trimethylelement-IVb groups. All 10 possible compounds are detected by  31 P NMR.

zeitschrift für naturforschung b

Substituentenaustauschreaktionen zwischen Tris(trimethylsilyl)phosphan und Trimethylgermanium- und Trimethylzinnchlorid / Scrambling Reactions Between Tris(trimethylsilyl)phosphane and Trimethylgermanium- and Trimethyltinchloride