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The layer silicates kaolinite, nacrite, dickite, halloysite as well as metal disulfides react with imidazole or methylimidazoles, yielding layer-intercalation-compounds; e.g. TiS 2 . 0,72 imidazole or Al 4 (OH) 8  Si 4 O 10  · 1.72 imidazole. In TiS 2  the organic guest molecules are arranged in bilayers, with the plane of their rings tilted against the layers of the host lattice. H-Substitution by -CH 3  on the nitrogen does not increase the spacing, while methyl-substitution on carbon-2 causes an increase of about 4 A.

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Neue Einlagerungsverbindungen von Kaolinit, Nakrit, Dickit, Halloysit und Titandisulfid mit Imidazol und Methylimidazol / New Layer Intercalation Compounds of Kaolinite, Nacrite, Dickite, Halloysite and Titandisulfide with Imidazole and Methylimidazole