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The dimeric complexes [R 2 PSOM(CO) 3 ] 2  1-4 (R = C 2 H 5 , C 6 H 5 ; M = Mn, Re) are nearly exclusively formed by reaction of the monothiophosphinic acids R 2 PSOH with the bromopentacarbonylmanganese and -rhenium compounds BrM(CO) 5  according to Eqn. (1). The monosubstitution products 5 and 6 are obtained from 3 and 4 with P(C 6 H 5 ) 3  in benzene according to Eqn. (2). The disubstituted complexes (C 6 H 5 ) 2 PSORe(CO) 3 [P(C 6 H 5 ) 3 ] 2  (7) and (C 6 H 5 ) 2 PSORe(CO) 2 [P(C 6 H 5 ) 3 ] 2  (8) are mainly formed by reaction of 4 with excess P(C 6 H 5 ) 3  in toluene according to Eqn. (3). The newly prepared compounds are discussed on the basis of their IR and mass spectra.

Das Verhalten von Thiophosphinsäuren gegenüber BrMn(CO) 5 und BrRe(CO) 5 / The Behaviour of Thiophosphinic Acids towards BrMn(CO) 5 and BrRe(CO) 5