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The reaction of C 3 F 7 Fe(CO) 3 [P(C 6 H 5 ) 3 ] I with liquid ammonia yields, dependend on the reaction-time C 3 F 7 Fe(CO) 2 (NH 3 ) 2 I and [C 3 F 7 Fe(CO) 2 (NH 3 ) 3 ] I. In the contrary, C 3 F 7 Fe(CO) 4  I undergoes ammonolysis forming NH 4 F, NH 4 I, NH 4 NCO and CO (NH 2 ) 2 . No stable iron-complex could be obtained.

zeitschrift für naturforschung b

Zur Kenntnis der Chemie der Metallcarbonyle und der Cyanokomplexe in flüssigem Ammoniak, XXVII.: Über die Reaktion von C 3 F 7 Fe(CO) 3 [P(C 6 H 5 ) 3 ]J und C 3 F 7 Fe(CO) 4 J mit flüssigem Ammoniak / About the Reaction of C 3 F 7 Fe(CO) 3 [P(C 6 H 5 ) 3 ] I and C 3 F 7 Fe(CO) 4 I with liquid Ammonia