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The origin of the positive Soret Cotton effect of myoglobin was calculated by Hsu and WOODY on the basis of a mechanism taking into account the coupling of the Soret and aromatic side-chain π—π* transitions. HUBER and coworkers have worked out the atomic coordinates of a monomeric insect hemoglobin which exhibits a negative Soret Cotton effect.

The Influence of the Aromatic Amino Acid Side-Chains on the Sign of the Soret Cotton Effect in Chironomus Hemoglobin (CTT III)