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The hitherto unknown dimeric halogen iron tricarbonyls [Fe(CO) 3 X] 2  (X = Br, I) have been prepared by reacting HBr or HI with Fe 2 (CO) 9  and by the photoreaction of Fe(CO) 5  with HBr. The properties of these compounds are discussed.

zeitschrift für naturforschung b

Di-μ-halogeno-bis(tricarbonyleisen): Über die Bildung dimerer Halogeneisentricarbonyle bei der thermischen und photochemischen Umsetzung von Eisencarbonylen mit Halogenwasserstoff / Di-μ-halogen-bis (tricarbonyliron) : Formation of Dimeric Halogen Iron Tricarbonyls in the Thermal and Photochemical Reaction of Iron Carbonyls with Hydrogen Halides