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The 20-eV-Mass spectra of eight methylene- and eight non-methylene-interrupted cis,cis-methyl-octadecadienoates as their tetra-O-trimethylsilyl derivatives are given. The fragmentation pattern dependent on the original position of double bonds and number of methylene-groups between the two double bonds is discussed.

zeitschrift für naturforschung b

Massenspektren synthetischer methylen- und nicht-methylen-unterbrochener cis, cis-Oktadecadiensäure-methylester als Tetra-O-trimethylsilyläther / Mass Spectra of Synthetic Methylene- and Non-Methylene-Interrupted cis-cis-Methyl-Octadecadienoates as Their Tetra-O-Trimethylsilylether