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Hydrazine in ethereal solution is oxidized to nitrogen by means of dichlorodisulfane, while the sulfane is reduced to sulfur. Intermediates of the oxidation of hydrazine could not be observed. By reaction of 1,2-dimethylhydrazine with dichlorodisulfane tetramethyl cyclotetrasulfurdihydrazide has been obtained.

zeitschrift für naturforschung b

Beiträge zur Chemie des Hydrazins und seiner Derivate, XXX / Über die Umsetzung von Hydrazin und 1.2-Dimethylhydrazin mit Dichlordisulfan / The Reaction of Hydrazine and 1,2-Dimethylhydrazine with Dichlorodisulfane