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The OH-radical adds to furan, thiophene and pyrrole in diffusion controlled reaction. The rate constants of these reactions and the spectra of the products were determined. The OH-addition products of furan and thiophene dissociate in alkaline solutions. The anions undergo ring scission:

zeitschrift für naturforschung b

Pulsradiolytische Untersuchung der oxydativen Ringöffnung von Furan, Thiophen und Pyrrol / Pulsradiolytic Investigations of the Oxydativ Ring Scission of Furan, Thiophen and Pyrrol