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The infrared and Raman spectra of aqueous alkaline Zn(II) solutions and of crystalline tri-, tetra- and hexahydroxo zincate(II) and tetra- and hexahydroxocadmate(II) salts, respectively, are reported and discussed. Between 5 ᴍ and 15 ᴍ NaOH concentrations only the tetrahedral [Zn(ΟΗ) 4 ] 2⊖ -ion is present in solution. Direct coordination of H 2 O to Zn(II) does not take place in an essential order of magnitude at any concentration

zeitschrift für naturforschung b

Schwingungsspektroskopische Untersuchungen an Hydroxokomplexen des Zinks und Cadmiums / Vibrational Spectroscopic Investigations of Hydroxy Complexes of Zinc and Cadmium