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Bis (dimethylamino) -boronhalides react with dibenzonitrile palladium-dichloride (C 6 H 5 CN)  2 PdCl 2  in a different manner. Bis (dimethylamino) -boronchloride forms, just like bis (dimethylamino) methylborane complexes of the type Cl 2 Pd [ (CH 3 )  2 N]  2 BX (X = Cl, CH 3 ). On the contrary the analogous bromo- and iodoboranes react with coordinated benzonitrile and form the diborylamine palladium complexes C 6 -C(X 2 ) -N{B[N(CH 3 ) 2 ] 2 } 2 PdX (X = Br, J) which probably are dimeric. The B -N-groups presumably act as π-ligands.

zeitschrift für naturforschung b

Metall-Bor-Verbindungen X / Metal Boron Compounds X l: Diborylamine als π-Liganden in Palladiumkomplexen / Diborylamines as π-Ligands in Palladium Complexes