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Phase equilibrium in the PrBr 3 -CsBr binary system was established from Differential Scanning Calorimetry (DSC). This system has two compounds, Cs 3 PrBr 6  and CsPr 2 Br 7 , and three eutectics located at molar fraction of PrBr 3  ( x  = 0 . 108; 850 K), ( x  = 0 . 453; 767 K), and ( x  = 0 . 757, 870 K), respectively. Cs 3 PrBr 6  undergoes a solid-solid phase transition at 726 K and melts congruently at 1051 K. CsPr 2 Br 7  undergoes a solid-solid phase transition at 835 K, and melts congruently at 896 K. The electrical conductivity of PrBr 3 -CsBr liquid mixtures was measured down to temperatures below solidification over the whole composition range. Results obtained are discussed in term of possible complex formation.

Phase Diagram and Electrical Conductivity of the PrBr 3 -CsBr Binary System